Asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol

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Asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol.

An efficient asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol is presented employing catalytic asymmetric conjugate addition and catalytic epoxide ring opening as the key steps. Their occurrence in deep sea hydrothermal vents has been confirmed by chromatographic comparison with natural samples.

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ژورنال

عنوان ژورنال: Organic & Biomolecular Chemistry

سال: 2013

ISSN: 1477-0520,1477-0539

DOI: 10.1039/c3ob27277j